Neymar will not captain Brazil during next month's Copa America, with Dani Alves handed the armband for the showpiece South American tournament on home soil.
Paris Saint-Germain superstar Neymar was named permanent Brazil captain by head coach Tite in September 2018, however, he has been replaced by 36-year-old club and country team-mate Alves.
In a statement released on Monday, the Brazilian Football Confederation (CBF) said: "The decision was communicated to Neymar by Tite on Saturday."
The announcement comes after a turbulent end to the season for Neymar at Ligue 1 champions PSG, where coach Thomas Tuchel has ruled out the former Barcelona star becoming captain.