Spain thumped Portugal 7-1 to move top of their group in the women's Nations League on Tuesday, while European champions England lost 3-2 in Belgium.
In Vigo, world champions Spain started fast as Salma Paralluelo opened the scoring on two minutes.
Double-reigning women's Ballon d'Or Aitana Bonmati flighted in a sublime second six minutes later, before adding a third on 12 minutes.
Alexia Putellas, the only other woman to hold two Ballon d'Or awards, scored Spain's fourth two minutes before the half-hour.
Mariona Caldentey slotted in a fifth in the 47th minute.
Putellas continued the rout on 51 minutes as she showcased her class with a perfect take on the turn and a composed finish.