Rafael Nadal will continue his quest to complete a calendar Grand Slam, while Katie Boulter is the headline act for Great Britain on day four at Wimbledon.
Nadal has already clinched the Australian and French Open crowns this season and is aiming to claim his first Wimbledon title since 2010.
The Spaniard, 36, takes on Lithuania's Ricardas Berankis in round two.
Boulter, though, will be first out on Centre Court on Thursday when she faces Czech sixth seed Karolina Pliskova.
The 25-year-old world number 118 is looking to reach the third round at the All England Club for the first time.