Champions League holders Liverpool travel to the Stadio San Paolo to face Napoli in their opening game of this season's competition.
The Reds head into the clash in fine fettle, having earned their fifth successive Premier League victory thanks to a 3-1 win over Newcastle - goals from Sadio Mane (2) and Mohamed Salah sealing all three points.
Napoli, meanwhile, cruised past Sampdoria 2-0 to record their second Serie A win of the season; Carlo Ancelotti's side showing their dominance in a performance that suggested they may well have the tools to fight Juventus for the league title.