Sevilla suffered a shock 2-0 defeat at home to Getafe in La Liga on Sunday, as the Andalusian club continued their unconvincing early form.
Angel was the thorn in the hosts' side, striking twice in the first half, deflating Sevilla's hopes of collecting points.
Espanyol continued their impressive early-season performances as they defeated Levante 1-0 in Catalonia.
Veteran winger Sergio Garcia was the hero, with his second half strike the difference between the sides.
There were also slim away victories for Alaves and Villarreal, who beat Real Valladolid and Leganes on the road by a solitary goal, respectively.