Luis Enrique's men lost 2-0 at the Vicente Calderon and are out of the Champions League as their poor recent run continues - and their best player was absent again on Wednesday.
There will be no treble this time for Barcelona. The Catalan club was dumped out of the Champions League by an intense and impressive Atletico side on Wednesday as Lionel Messi went missing in Madrid. Suddenly, nothing is going right for Luis Enrique's men.
Barca won the first leg 2-1, but only took control of that match after Fernando Torres was dismissed for two bookable offenses.