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Liverpool crashed out of the UEFA Champions League after losing 3-2 after extra time against Atletico Madrid on Wednesday at Anfield.
The result allowed the La Liga giants to advance 4-2 on aggregate, with the holders running out of steam in the last 16.
Paris Saint-Germain eliminated Borussia Dortmund 3-2 on aggregate after winning 2-0 in the French capital.
Atletico and PSG join RB Leipzig and Atalanta in the next round after they knocked out Tottenham Hotspur and Valencia, respectively, on Tuesday.
Wednesday's Results
Liverpool 2-3 Atletico (Atleti win 4-2 on aggregate)
PSG 2-0 BVB (PSG win 3-2 on aggregate)
Wednesday Recap
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Liverpool couldn't find a way into the quarter-finals against a dogged Atleti team intent on frustrating the Premier League leaders.