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Angel Di Maria was the architect of Barcelona's downfall in the UEFA Champions League round of 16, with the attacker grabbing a brace in a 4-0 victory in the first leg on Tuesday.
Julian Draxler and Edinson Cavani completed the shocking scoreline as Lionel Messi and his team-mates collapsed in Paris.
Messi remains the tournament's top scorer on 10 goals and will get a chance to increase his total in the return leg at the Camp Nou.
Benfica defeated Borussia Dortmund in the night's other last-16 battle, winning the first leg 1-0 as Konstantinos Mitroglou found the back of the net.