The hosts, who won Euro 2020 just three months ago, will arguably be favourites to claim the silverware after recently breaking the world record for the longest unbeaten run in men’s international football.
Nevertheless, David De Gea’s Spain, a France side containing Raphael Varane, Paul Pogba and Anthony Martial, plus the always-dangerous Belgium will have other ideas.
Here’s your guide to the upcoming games and what the Nations League is all about...
WHAT IS THE NATIONS LEAGUE?
Introduced as a way of adding more meaningful games to the international calendar, the Nations League splits UEFA’s 55 member nations into four leagues, based on their coefficients.