Sixty-six teams are in the hat, with two replays set for next week - Charlton Athletic versus Stockport County, and Dagenham & Redbridge versus Gillingham.
The ceremony will take place at Liverpool's Anfield stadium, due to the fact they are the holders, on Monday night.
It is scheduled to happen between 19:00 GMT and 19:30 GMT, and we will, of course, let you know which side the Reds will meet via all our official channels.
The third-round games are to take place around the weekend of 7/8 January 2023, and it represents Erik ten Hag's first foray into the famous competition.