The Reds overcame Brighton & Hove Albion 7-6 on penalties after a gruelling goalless draw over 120 minutes, with Victor Lindelof steering home the decisive spot-kick after Solly March blazed over.
With City, still battling for a Treble, beating Sheffield United 3-0 with a Riyad Mahrez hat-trick, the two clubs have a major date to look forward to next month and a third trip to Wembley this term for Erik ten Hag's men.
We have faced the Blues twice at the stadium before, both matches taking place in 2011. After losing the FA Cup semi-final 1-0, with Paul Scholes sent off and Yaya Toure scoring the only goal of the game, we began the following season with a thrilling 3-2 victory in the Community Shield.