Goalkeeper Rachael Laws, who arrived from Reading in the summer, has taken the No.1 jersey.
Danish striker Amalie Thestrup will play this season as the Reds' new No.9, while new full-back Taylor Hinds is No.12.
There are also changes among the rest of the squad, with last year's top scorer Rinsola Babajide switching to the No.10 shirt – a change from her previous No.20.
Elsewhere, full-back Becky Jane will take No.2 this term, having worn No.22 in 2019-20.
LFC Women squad numbers 2020-21
1.