The former Reds forward will feature alongside the likes of Steven Gerrard, Jamie Carragher, Dirk Kuyt, Kaka, Andrea Pirlo and Paolo Maldini in the LFC Foundation charity match, which will be broadcast live and for free on LFCTV.
Garcia scored 30 goals in 121 games for Liverpool and was one of the heroes of Istanbul, when the Reds beat AC Milan in the 2005 Champions League final.
The Spaniard had a habit of producing vital strikes and though his legs are a little older these days, his desire to score at the Kop End has not diminished.