The match will kick off at 2pm on Saturday (August 31) at Prenton Park.
Rangers Women play in the Scottish Women’s Premier League and a familiar face will be among the group travelling to Merseyside.
Former Reds defender Gregory Vignal was appointed the head coach of Rangers Women this summer after a spell with the club’s youth set-up.
The Frenchman made 20 first-team appearances for the Reds between 2001 and 2003 before several loan spells including one at Glasgow Rangers. He left Anfield on a permanent basis in 2005.
Saturday’s game is open only to Liverpool FC Women season ticket holders, who will be admitted free of charge.