The Reds are set to host the La Liga outfit at Anfield in their penultimate warm-up game before the Premier League campaign begins.
Kick-off is 4pm BST and you can watch the full match live on LFCTV GO, with our coverage beginning at 3pm.
Visit www.liverpoolfc.com/watch to subscribe now and use code 2122GOFREE to get your first month free. T&Cs apply.
Fans in the UK and Republic of Ireland can also tune in live on LFCTV via Sky and Virgin Media.