Jürgen Klopp’s side host the La Liga team at Anfield in their final friendly before beginning the new Premier League campaign.
You can see the full 90 minutes live on LFCTV GO, with kick-off at 7pm BST and our coverage getting under way half an hour earlier.
Visit www.liverpoolfc.com/watch to subscribe now and use code 2122GOFREE to get your first month free. T&Cs apply.
Fans in the UK and Republic of Ireland can also watch the match live on LFCTV via Sky and Virgin Media.