A host of greats are set to line up on both sides – including the likes of Cafu, Jamie Carragher, Robbie Fowler, Steven Gerrard, Kaka, Dirk Kuyt and Paolo Maldini – for a 3pm GMT kick-off at Anfield.
Exclusive build-up from the stadium will begin at 1.30pm, including pre-match interviews with the stars involved and case studies detailing the importance of the funds raised.
The whole game will be broadcast live and for free on LFCTV as part of a promotion running until 6am GMT on Tuesday March 26.
Alternatively, you can tune in online via LFCTV GO or access a free live stream from Anfield on YouTube or Facebook.