The Brazilian denied Arkadiusz Milik in the 92nd minute at Anfield last December to secure a 1-0 victory in matchday six for the Reds and confirm their passage to the last 16.
After winning the competition in June, Jürgen Klopp's side were paired with the Serie A outfit in the pools once again - an opponent in which Alisson has fond memories of.
“They are part of the story of my career," the goalkeeper told The Independent.
"In March 2018, Roma had an away game in Naples and it was an awesome one for me as I made 11 saves in a big defensive performance, which is really important against Napoli.