The reigning Italian champions Juventus face rivals Inter in the fourth round of fixtures while the Torino derby falls on matchday 16, as Napoli take on Pescara in their opener
Juventus starts its hunt for a sixth consecutive Serie A title with a home game against Fiorentina.
The reigning champion takes on rival Inter at San Siro on matchday four in what will be its first major test of the 2016-17 campaign, before facing AC Milan on its second trip to San Siro in week nine.
Massimiliano Allegri's men host last season's runner-up Napoli on matchday 11, with Roma awaiting in Turin five matches later.