The Turkish champion has confirmed that it has opened negotiations with the Spanish club and left back, who featured just eight times in La Liga last season.
Besiktas has announced that the club is in talks with Barcelona over the signing of Adriano Correia.
The Turkish champion is keen to sign a new left back following the departure of Ismail Koybasi to Fenerbahce and the side has earmarked Adriano as the perfect replacement.
The 31-year-old has been deemed surplus to requirements at Barcelona after the signing of Lucas Digne and Besiktas is keen to lure him to Istanbul.